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Beilstein J. Org. Chem. 2018, 14, 2125–2145, doi:10.3762/bjoc.14.187
Graphical Abstract
Scheme 1: Triarylbismuth compounds, that serve as examples for the investigation of bismuth···π interactions ...
Figure 1: Ball and stick model of a fragment of a) the zig-zag chain of a 1D arrangement of Ph3Bi (1a). Hydro...
Figure 2: Ball and stick model of a fragment of the zig-zag type arrangement of Ph3Bi (1b) [45], view along the b...
Figure 3: Ball and stick model of Ph3Bi (1c) showing: a) non-centrosymmetric dimers formed via two Bi···π are...
Figure 4: Wire and stick representation of (C6H4-CH═CH2-4)3Bi (2a) showing: a) zig-zag chains of 1D ribbons f...
Figure 5: Wire and stick model of (C6H4-CH═CH2-4)3Bi (2b) showing: a) the formation of 1D ribbons build via t...
Figure 6: Molecular structure of (C6H4-OMe-4)3Bi (3) showing: a) Thermal ellipsoids that are set at 50% proba...
Figure 7: Wire and stick model of (C6H3-t-Bu2-3,5)3Bi (4) showing a 3D network build via four C–Ht-Bu···π (ar...
Figure 8: Wire and stick model of (C6H3-t-Bu2-3,5)2BiCl (5) showing a fragment of the 1D arrangement, view al...
Figure 9: Computed interaction potentials of the distance scan for the idealized BiPh3–benzene complex. E(int...
Figure 10: a) The BiPh3 potential energy curve for idealized interaction structures compared to the interactio...
Figure 11: Structures of studied BiPh3 tetramers extracted from the crystal structure of polymorph 1a. Etetram...
Figure 12: Detailed structures of selected dimers extracted from the crystal structure of polymorph 1a and dis...
Figure 13: Structures of studied BiPh3 tetramers extracted from the crystal structure of polymorph 1b. See Figure 11 fo...
Figure 14: Detailed structures of selected dimers extracted from the crystal structure of polymorph 1b and dis...
Figure 15: Structures of studied BiPh3 tetramers extracted from the crystal structure of polymorph 1c. See Figure 11 fo...
Figure 16: Detailed structures of selected dimers extracted from the crystal structure of the polymorph 1c and...
Figure 17: Distortion energies of monomers (Eprep, blue triangles) and interaction energies of Bi···π and π-st...